標準編號:	DB11/ 3005-2017
中文名稱:	建筑類涂料與膠粘劑揮發性有機化合物含量限值標準
英文名稱:	Limit standards of volatile origanic compounds of architectural coatings and adhesives
行業分類:	DB    地方標準
發布機構:	北京市質量技術監督局
發布日期:	2017-04-12
實施日期:	2017-9-1
標準狀態:	superseded
被新標準替代:	DB11/ 1983-2022 建筑類涂料與膠粘劑揮發性有機化合物含量限值標準
翻譯語言:	英文
文件格式:	PDF
中文字符數:	8000 字
翻譯價格(元):	600.0
交付時間:	付款后 1 個工作日

Codeofchina.com is in charge of this English translation. In case of any doubt about the English translation, the Chinese original shall be considered authoritative. In order to boost the implementation of coordinated development of the Beijing-Tianjin-Hebei Region, Beijing Municipal Environmental Protection Bureau, Tianjin Environmental Protection Bureau, Hebei Provincial Environmental Protection Bureau, Administration of Quality and Technology Supervision, Tianjin Market and Quality Supervision Administration, and Hebei Provincial Administration of Quality and Technical Supervision have jointly organized and formulated this provincial standard, which is applicable to the Beijing-Tianjin-Hebei Region and issued hereby. The full text of this standard is mandatory. This standard is developed in accordance with the rules given in GB/T 1.1-2009. This standard was proposed by and is under the jurisdiction of Beijing Municipal Environmental Protection Bureau. This standard is jointly organized and implemented by Beijing Municipal Environmental Protection Bureau, Beijing Administration for Industry and Commerce, Beijing Municipal Administration of Quality and Technology Supervision, and Beijing Municipal Commission of Housing and Urban-Rural Development. Introduction This standard is formulated with a view to implementing Regulations of Beijing Municipality on Prevention and Control of Air Pollution so as to reduce the emission of volatile organic compounds during the application of architectural coatings and adhesives and improve regional atmospheric environment quality. Limit Standards of Volatile Organic Compounds of Architectural Coatings and Adhesives 1 Scope This standard specifies contents such as limit requirements, inspection method, inspection rules, and package marking of volatile organic compounds of architectural coatings and adhesives. This standard is applicable to all types of architectural coatings and adhesives produced, sold and applied in Beijing-Tianjin-Hebei region. 2 Normative References The following documents are indispensable for the application of this standard. For dated reference, only the edition cited applies. For undated references, the latest edition (including all amendments) of the referenced documents applies. GB/T 3186-2006 Paints, Varnishes and Raw Materials for Paints and Varnishes - Sampling GB/T 6750-2007 Paints and Varnishes - Determination of Density - Pyknometer Method (ISO 2811-1:1997, Paints and Varnishes - Determination of Density - Part 1: Pyknometer Method, IDT) GB/T 9754-2007 Paints and Varnishes - Determination of Specular Gloss of Non-metallic Paint Films at 20°, 60°and 85° (ISO 2813:1994, IDT) GB 24408-2009 Limit of Harmful Substances of Exterior Wall Coatings GB 18582-2008 Indoor Decorating and Refurbishing Materials - Limit of Harmful Substances of Interior Architectural Coatings GB/T 22374-2008 Floor Coatings GB/T 23986-2009 Paints and Varnishes - Determination of Volatile Organic Compound (VOC) Content - Gas-chromatographic Method GB/T 8170-2008 Rules of Rounding off for Numerical Values & Expression and Judgement of Limiting Values GB 30981-2014 Limit of Harmful Substances of Anticorrosion Coatings for Construction Steel Structure GB 18583-2008 Indoor Decorating and Refurbishing Materials - Limit of Harmful Substances of Adhesives JC 1066-2008 Limit of Harmful Substances of Building Waterproof Coatings 3 Terms and Definitions For the purposes of this document, the following terms and definitions apply. 3.1 volatile organic compounds (VOC) any organic compounds of which the initial boiling point is lower than or equal to 250℃ under standard atmosphere pressure of 101.3kPa 3.2 volatile organic compounds content (VOC content) content of volatile organic compounds obtained by testing the products with specified method Note 1: as for the exterior wall coatings, interior wall coatings, volatile-curing waterproof coatings, water-based floor coatings, water-based architectural anticorrosive coatings, and water-based adhesives, the volatile organic compounds content is that after moisture content is deducted from the product, expressed in gram per liter (g/L). Note 2: as for the reaction-curing waterproof coatings, solvent-based floor coatings, solvent-free floor coatings, solvent-based architectural anticorrosive coatings, and solvent-based adhesives, the volatile organic compounds content is that without deducting the moisture content from the product, expressed in gram per liter (g/L). Note 3: the volatile organic compounds content of the putty for exterior and interior walls is that without deducting the moisture content from the product, expressed in gram per kilogram (g/kg). 3.3 architectural coatings coatings used for architectural industry and relevant fields for protection and decoration, including exterior wall coatings, interior wall coatings, waterproof coatings, floor coatings, and architectural anticorrosive coatings in this standard 3.4 architectural adhesives adhesives, including solvent-based adhesives, water-based adhesive and body-type adhesives in this standard, which are used for architectural industry and relevant fields to bind the adherend together by pasting 3.5 heavy-duty coatings coatings that are applicable in harsh corrosive environment and have long-lasting service life 4 Limit Requirements The content of volatile organic compounds in the products shall be in accordance with those specified in Table 1. Table 1 Limit Requirements for Volatile Organic Compounds Content Product type Content limit Exterior wall coatings (g/L) Finish paints a Priming paints a Putty b ≤100 ≤80 ≤10 g/kg Interior wall coatings (g/L) Finish paints a Priming paints a Putty b Gloss (60°)≤10 Gloss (60°)>10 ≤50 ≤80 ≤50 ≤10 g/kg Waterproof coatings (g/L) Volatile-curing waterproof coatings a Reaction-curing waterproof coatings c Epoxy resin modified waterproof coatings Polyurea waterproof coatings Polyurethane waterproof coatings ≤10 ≤150 ≤50 ≤100 Floor coatings(g/L) Water-based a Solvent-based c, d Solvent-free ≤120 ≤420 ≤60 Architectural anticorrosive coatings(g/L) Water-based a Solvent-based c, e ≤150 ≤420 Solvent adhesives(g/L)c SBS adhesives ACR adhesives Other adhesives ≤600 ≤550 ≤650 Water-based adhesives (g/L)a Polyvinyl acetate adhesives Formal adhesives Rubber adhesives Polyurethanes adhesives VAE emulsion adhesives ACR adhesives Other adhesives ≤100 ≤150 ≤150 ≤100 ≤100 ≤100 ≤150 Body-type adhesives (g/kg) Silicone (including MS) adhesives Polyurethanes adhesives Polysulfide adhesives Epoxy adhesives ≤100 ≤50 ≤50 ≤50 a Dilution and mixture ratio is not considered for exterior wall coatings, interior wall coatings, volatile-curing waterproof coatings, water-based floor coatings, water-based architectural anticorrosive coatings and water-based adhesives. b Dilution and mixture ratio is not considered for paste putty used for exterior and interior walls. As for powdery putty, for the purpose of testing, the powder shall be mixed with other liquids such as water or adhesives according to the construction mixture ratio specified for the product. Where the construction mixture ratio is within a certain range, the testing shall be carried out after mixing with the minimum amount of water and the maximum amount of other liquids such as adhesives. c The reaction-curing waterproof coatings, solvent-based floor coatings, solvent-based architectural anticorrosive coatings and solvent-based adhesives shall be tested after being mixed according to the construction mixture ratio specified for the products. Where the diluent consumption is within certain range, determination shall be carried out after mixing the products according to the maximum dilution ratio specified by the construction mix ratio. d It is only applicable to solvent-based floor coatings produced in Tianjin and Hebei Province; solvent-based floor coatings produced in Beijing shall be subjected to the requirements of Action Plan of Cleaning Air of Beijing and related policies; floor coatings sold and used in Beijing-Tianjin-Hebei region shall be in accordance with the content limit for water-based and solvent-free coatings. e It only applicable to solvent-based architectural anticorrosive coatings produced, sold and used in Tianjin and Hebei Province, as well as solvent-based heavy-duty coatings used in municipal and traffic facilities in Beijing in cases where heavy anti-corrosion technology is necessary; the solvent-based architectural anticorrosive coatings produced in Beijing shall be subjected to the requirements of Action Plan of Cleaning Air of Beijing and related policies ; the architectural anticorrosive coatings which are sold and used (except for the above-mentioned heavy-duty anti-corrosion coating) shall be in accordance with the content limit for water-based anticorrosive coatings. 5 Inspection Method 5.1 Sampling The product shall be sampled in accordance with the requirements of GB/T 3186-2006. 5.2 Test method 5.2.1 The volatile organic compounds (VOC) in exterior wall coatings shall be tested in accordance with those specified in Annex A, GB 24408-2009, wherein the moisture content and density shall be tested in accordance with Annex B, GB 24408-2009 and GB/T 6750-2007 respectively. The test result of priming paint and finish paint shall be calculated in accordance with A.7.2 in Annex A, GB 24408-2009, and that of putty products shall be calculated in accordance with A.7.1 in Annex A, GB 24408-2009. Note: moisture content and density tests are not applicable to all the putty samples. 5.2.2 The volatile organic compounds (VOC) in interior wall coatings and volatile-curing waterproof coatings shall be tested in accordance with Annex A, GB 18582-2008, wherein the moisture content and density shall be tested in accordance with Annex B, GB 18582-2008 and GB/T 6750-2007 respectively. The test results of priming paints and finish paints shall be calculated in accordance with A.7.2 in Annex A, GB 18582-2008, and that of putty products shall be calculated in accordance with A.7.1 in Annex A, GB 18582-2008. Note: moisture content and density tests are not applicable to all the putty samples. 5.2.3 The film gloss of interior wall coatings shall be tested in accordance with GB/T 9754-2007 with the testing conditions of (105±2)℃ and a drying time of 2h. 5.2.4 The volatile organic compounds (VOC) in reaction-curing waterproof coatings shall be tested in accordance with Annex A, JC 1066-2008. 5.2.5 The volatile organic compounds (VOC) in floor coatings shall be tested in accordance with GB/T 22374-2008. 5.2.6 The volatile organic compounds (VOC) in water-based architectural anticorrosive coatings shall be tested in accordance with GB/T 23986-2009, wherein the moisture content and density shall be tested in accordance with Annex B, GB 18582-2008 and GB/T 6750-2007 respectively. The test results of coating products shall be calculated in accordance with 10.4, GB/T 23986-2009. 5.2.7 The volatile organic compounds (VOC) in solvent-based architectural anticorrosive coatings shall be tested in accordance with Annex A, GB 30981-2014.

Foreword i Introduction i 1 Scope 2 Normative References 3 Terms and Definitions 4 Limit Requirements 5 Inspection Method 6 Inspection Rules 7 Package Marking Annex A (Informative) Examples for Contents of Supplementary Package Marking for Architectural Coatings and Adhesives

ICS 13.040.40 Z60 北京市地方標準 DB 11/ 3005—2017 建筑類涂料與膠粘劑揮發性有機化合物 含量限值標準 Limit standards of volatile organic compounds of architectural coatings and adhesives 2017-04-12發布 2017-09-01實施 北京市質量技術監督局 發布 前 言 為推進京津冀協同發展戰略實施，北京市環境保護局、天津市環境保護局、河北省環境保護廳、北京市質量技術監督局、天津市市場和質量監督管理委員會、河北省質量技術監督局共同組織制定本地方標準，在京津冀區域內適用，現予發布。 本標準為全文強制。 本標準依據GB/T 1.1-2009給出的規則起草。 本標準由北京市環境保護局提出并歸口。 本標準起草單位： （北京組）北京市環境保護科學研究院、北京建筑材料檢驗研究院有限公司、北京建筑大學。 （天津組）天津市環境監測中心、北京市環境保護科學研究院。 （河北組）河北海航企業管理咨詢有限公司、河北安億環境科技有限公司、河北環學環保科技有限公司、河北省環境科學學會、北京市環境保護科學研究院、河北潤峰環境檢測服務有限公司、河北晨陽工貿集團有限公司、衡水新光化工有限責任公司、石家莊市油漆廠、河北省粘接與涂料協會、北京惠盟創潔環保科技有限公司。 本標準主要起草人： （北京組） 聶磊、高美平、袁勛、高喜超、檀春麗、閆磊、張瀾夕、杜曉麗、申前進、邢可欣 （天津組） 鄧小文、關玉春、吳宇峰、聶磊、崔連喜、張肇元、王效國、楊虹、王琳、劉琨 （河北組）李占廣、馬貴寶、于海、程娜、聶磊、耿耀宗、耿樹行、于欣沛、胡中源、田海寧、凌芹、吳唐健、馬瑞蘭、賈小芳、劉芳萍、柳坤然 本標準由北京市環境保護局、北京市工商行政管理局、北京市質量技術監督局、北京市住房和城鄉建設委員會共同組織實施。 引 言 為貫徹《北京市大氣污染防治條例》，降低建筑類涂料與膠粘劑使用過程揮發性有機化合物的排放，改善區域大氣環境質量，制定本標準。 建筑類涂料與膠粘劑揮發性有機化合物含量限值標準 1 范圍 本標準規定了建筑類涂料與膠粘劑中揮發性有機化合物含量限值要求、檢驗方法、檢驗規則、包裝標志等內容。 本標準適用于京津冀區域內生產、銷售和使用的各類建筑類涂料與膠粘劑。 2 規范性引用文件 下列文件對于本標準的應用是必不可少的。凡是注日期的引用文件，僅所注日期的版本適用于本標準。凡是不注日期的引用文件，其最新版本（包括所有的修改單）適用于本文件。 GB/T 3186-2006 色漆、清漆和色漆與清漆用原材料取樣 GB/T 6750-2007 色漆和清漆 密度的測定 比重瓶法(ISO 2811-1:1997, Panits and varnishes-Determination of density-Part 1:Pyknometer method, IDT) GB/T 9754-2007 色漆和清漆 不含金屬顏料的色漆漆膜的20°、60°和85°鏡面光澤的測定（ISO 2813:1994，IDT) GB 24408-2009 建筑用外墻涂料中有害物質限量 GB 18582-2008 室內裝飾裝修材料 內墻涂料中有害物質限量 GB/T 22374-2008 地坪涂裝材料 GB/T 23986-2009 色漆和清漆 揮發性有機化合物（VOC）含量的測定 氣相色譜法 GB/T 8170-2008 數值修約規則與極限數值的表示和判定 GB 30981-2014 建筑鋼結構防腐涂料中有害物質限量 GB 18583-2008 室內裝飾裝修材料 膠粘劑中有害物質限量 JC 1066-2008 建筑防水涂料中有害物質限量 3 術語和定義 下列術語和定義適用于本文件。 3.1 揮發性有機化合物（VOC）volatile organic compounds 在101.3kPa標準大氣壓下，任何初沸點低于或等于250℃的有機化合物。 3.2 揮發性有機化合物含量（VOC含量）volatile organic compounds content 按規定的測試方法測試產品所得到的揮發性有機化合物的含量。 注1：外墻涂料、內墻涂料、揮發固化型防水涂料、水性地坪涂料、水性建筑防腐涂料、水基型膠粘劑為產品扣除水分后的揮發性有機化合物的含量，以克每升（g/L）表示。 注 2：反應固化型防水涂料、溶劑型地坪涂料、無溶劑型地坪涂料、溶劑型建筑防腐涂料、溶劑型膠粘劑為產品不扣除水分的揮發性有機化合物的含量，以克每升（g/L）表示。 注 3：外墻與內墻膩子為產品不扣除水分的揮發性有機化合物含量，以克每千克（g/kg）表示。 3.3 建筑類涂料 architectural coatings 用于建筑行業及相關領域，起保護、裝飾作用的涂料。本標準包括外墻涂料、內墻涂料、防水涂料、地坪涂料與建筑防腐涂料。 3.4 建筑類膠粘劑 architectural adhesives 用于建筑行業及相關領域，通過粘和作用，使被粘物結合在一起的膠粘劑。本標準包括溶劑型膠粘劑、水基型膠粘劑與本體型膠粘劑。 3.5 重防腐涂料 heavy-duty coatings 能在嚴酷的腐蝕環境下應用，并具有長效使用壽命的涂料。 4 限值要求 產品中揮發性有機化合物含量應符合表 1 的要求。 表1 揮發性有機化合物含量限值要求 產品類型 含量限值 外墻涂料（g/L） 面漆a 底漆a 膩子b ≤100 ≤80 ≤10 g/kg 內墻涂料（g/L） 面漆a 底漆a 膩子b 光澤（60°）≤10 光澤（60°）＞10 ≤50 ≤80 ≤50 ≤10 g/kg 防水涂料（g/L） 揮發固化型防水涂料a 反應固化型防水涂料c 環氧樹脂改性防水涂料 聚脲防水涂料 聚氨酯防水涂料 ≤10 ≤150 ≤50 ≤100 地坪涂料（g/L） 水性a 溶劑型c，d 無溶劑型 ≤120 ≤420 ≤60 建筑防腐涂料（g/L） 水性a 溶劑型c，e ≤150 ≤420 溶劑型膠粘劑（g/L）c SBS膠粘劑 丙烯酸酯類膠粘劑 其他膠粘劑 ≤600 ≤550 ≤650 表 1 （續） 水基型膠粘劑（g/L）a 聚乙酸乙烯酯類膠粘劑 縮甲醛類膠粘劑 橡膠類膠粘劑 聚氨酯類膠粘劑 VAE乳液類膠粘劑 丙烯酸酯類膠粘劑 其他類膠粘劑 ≤100 ≤150 ≤150 ≤100 ≤100 ≤100 ≤150 本體型膠粘劑（g/kg） 有機硅類（含MS） 膠粘劑 聚氨酯類膠粘劑 聚硫類膠粘劑 環氧類膠粘劑 ≤100 ≤50 ≤50 ≤50 a 外墻涂料、內墻涂料、揮發固化型防水涂料、水性地坪涂料、水性建筑防腐涂料、水基型膠粘劑不考慮稀釋配比。 b 外墻與內墻膩子中膏狀膩子不考慮稀釋配比。粉狀膩子按照產品規定的施工配比將粉體與水或膠粘劑等其他液體混合后測試。如施工配比在某一范圍時，應按照水用量最小、膠粘劑等其他液體用量最大的施工配比混合后測試。 c 反應固化型防水涂料、溶劑型地坪涂料、溶劑型建筑防腐涂料、溶劑型膠粘劑按照產品規定的施工配比混合后測試。如稀釋劑的使用量為某一范圍時，應按照產品施工配比規定的最大稀釋比例混合后進行測試。 d 僅適用于在天津市和河北省生產的溶劑型地坪涂料；北京市生產的溶劑型地坪涂料應按照北京市清潔空氣行動計劃及相關政策執行；京津冀區域銷售和使用的地坪涂料應符合水性和無溶劑型的含量限值。 e 僅適用于在天津市和河北省生產、銷售、使用的溶劑型建筑防腐涂料，以及北京市在市政、交通設施等必須采用重防腐工藝時所使用的溶劑型重防腐涂料；北京市生產的溶劑型建筑防腐涂料應按照北京市清潔空氣行動計劃及相關政策執行，銷售和使用的建筑防腐涂料（除前述重防腐情況外）應執行水性防腐涂料的含量限值。 5 檢驗方法 5.1 取樣 產品取樣按照 GB/T 3186-2006 的規定進行。 5.2 試驗方法 5.2.1 外墻涂料中揮發性有機化合物（VOC）的檢測按照GB 24408-2009附錄A的規定進行，其中水分含量的檢測按照GB 24408-2009附錄B進行，密度的檢測按照GB/T 6750-2007進行。底漆和面漆產品測試結果的計算按照GB 24408-2009附錄A中A.7.2進行，膩子產品測試結果的計算按照GB 24408-2009附錄A中A.7.1進行。 注：所有膩子樣品不做水分含量和密度的測試。 5.2.2 內墻涂料與揮發固化型防水涂料中揮發性有機化合物（VOC）的檢測按照GB 18582-2008附錄A的規定進行，其中水分含量的檢測按照GB 18582-2008附錄B進行，密度的檢測按照GB/T 6750-2007進行。底漆和面漆產品測試結果的計算按照GB 18582-2008附錄A中A.7.2進行，膩子產品測試結果的計算按照GB 18582-2008附錄A中A.7.1進行。 注：所有膩子樣品不做水分含量和密度的測試。 5.2.3 內墻涂料涂膜光澤的檢測按照GB/T 9754-2007進行，測試條件為（105±2）℃，烘干2小時。 5.2.4 反應固化型防水涂料中揮發性有機化合物（VOC）的檢測按照JC 1066-2008附錄A的規定進行。 5.2.5 地坪涂料中揮發性有機化合物（VOC）的檢測按照GB/T 22374-2008的規定進行。 5.2.6 水性建筑防腐涂料中揮發性有機化合物（VOC）的檢測按照GB/T 23986-2009的規定進行，其中水分含量的檢測按照GB 18582-2008附錄B進行，密度的檢測按照GB/T 6750-2007進行。涂料產品測試結果的計算按照GB/T 23986-2009中10.4進行。 5.2.7 溶劑型建筑防腐涂料中揮發性有機化合物（VOC）的檢測按照GB 30981-2014附錄A的規定進行。 5.2.8 膠粘劑中揮發性有機化合物（VOC）的檢測按照GB 18583-2008附錄F的規定進行。 6 檢驗規則 6.1 檢驗項目 6.1.1 本標準所列的全部要求均為型式檢驗項目。 6.1.2 在正常生產情況下，每年至少進行一次型式檢驗。 6.1.3 有下列情況之一時應隨時進行型式檢驗： ——新產品最初定型時； ——生產配方、工藝、關鍵原材料來源及產品施工配比有較大改變時； ——停產三個月后又恢復生產時。 6.1.4 銷售單位在京津冀區域內銷售本標準規定的產品，銷售單位應能提供有效的型式檢驗報告。 6.2 檢驗結果 6.2.1 檢驗結果的判定按照GB/T 8170-2008 中修約值比較法進行。 6.2.2 粉狀膩子、反應固化型防水涂料、溶劑型地坪涂料、溶劑型建筑防腐涂料、溶劑型膠粘劑產品報出檢驗結果時應同時注明產品明示的施工配比。 6.2.3 檢驗結果達到本標準表1的要求時，產品為符合本標準要求。 7 包裝標志 7.1 2017年9月1日起，在京津冀區域內生產、銷售本標準規定的產品，除原有產品說明外，需要在包裝標志上補充標明以下內容(示例參照附錄A)： a) 本標準規定的產品類型和用途。 b) 產品所含揮發性有機化合物含量，可以選用以下兩種形式之一表述： 1) 揮發性有機化合物含量值； 2) 揮發性有機化合物含量不超過表1規定的限值。 c) 對于施工時需要稀釋的產品，則須顯示推薦的稀釋溶劑和稀釋量（對于用水稀釋的膠粘劑或建筑類涂料無需說明）。對于由雙組分或多組分配套組成的產品，則須顯示各組分的施工配比。 附 錄 A （資料性附錄） 建筑類涂料與膠粘劑補充包裝標志內容示例 A.1 在京津冀區域生產、銷售建筑類涂料與膠粘劑，需補充的包裝標志內容示例見表A.1 表A.1 建筑類涂料與膠粘劑需補充包裝標志內容示例 產品類型 外墻涂料 產品大類 底漆 產品小類 / 產品用途 適用于別墅、酒店、學校、醫院、寫字樓和家居外墻的裝飾和保護。 揮發性有機化合物含量 揮發性有機化合物含量 X g/L 或 揮發性有機化合物含量 ≤ X g/L 推薦稀釋劑 / 稀釋比例 / 施工配比 / 產品類型 建筑防腐涂料 產品大類 溶劑型建筑防腐涂料 產品小類 / 產品用途 適用于家裝、公共環境、建筑混凝土和鋼結構表面防護與裝飾。 揮發性有機化合物含量 揮發性有機化合物含量 X g/L 或 揮發性有機化合物含量 ≤ X g/L 推薦稀釋劑 聚氨酯涂料稀釋劑 稀釋比例 稀釋劑/涂料 ≤ X 施工配比 / 產品類型 膠粘劑 產品大類 溶劑型膠粘劑 產品小類 聚氨酯膠粘劑 產品用途 適用于室內外裝飾裝修和建筑施工工程的粘結密封。 揮發性有機化合物含量 揮發性有機化合物含量 X g/L 或 揮發性有機化合物含量 ≤ X g/L 推薦稀釋劑 / 稀釋比例 / 施工配比 組分A：組分B = 1：X